$\Rightarrow \mathrm{VT}=\mathrm{constant}$
$\Rightarrow \mathrm{V}$ is inversely proportional to $\mathrm{T}$
$\Rightarrow$ expansion causes increase in $\mathrm{V}$
$\Rightarrow$ it leads to decrease in $T$
$\Rightarrow$ gas is cooled
So correct option is $d$


