આપેલ : $\left(\mathrm{K}_{\mathrm{r}}\right)_{\text {water }}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$.
એસિટિક એસિડની ઘનતા $1.2 \mathrm{~g} \mathrm{moL}^{-1}$.
પાણી નું મોલર દળ $=18 \mathrm{~g} \mathrm{~mol}^{-1}$.
એસિટિક એસિડ નું મોલર દળ = $60 \mathrm{~g} \mathrm{~mol}^{-1}$, પાણીની ધનતા=1 $\mathrm{g} \mathrm{cm}^{-3}$
એસિટિક એસિડ $\mathrm{CH}_3 \mathrm{COOH} \rightleftharpoons \mathrm{CH}_3 \mathrm{COO}^{\ominus}+\mathrm{H}^{\oplus}$ તરીકે વિયોજિત થાય છે.
$=5 \mathrm{ml} \times 1.2 \mathrm{~g} / \mathrm{ml}$
$=6 \mathrm{gm}$
$\mathrm{n}_{\mathrm{CH}_3 \mathrm{COOH}}=\frac{6}{60}=0.1 \mathrm{~mol}$
$\mathrm{~m}_{\mathrm{CH}_3 \mathrm{COOH}} \approx \mathrm{M}_{\mathrm{CH}_3 \mathrm{COOH}}=\frac{0.1}{1}=0.1 \mathrm{M}$
$\mathrm{CH}_3 \mathrm{COOH} \rightleftharpoons \mathrm{CH}_3 \mathrm{COO}^{-}+\mathrm{H}^{+}$
$\mathrm{C}$
$\mathrm{C}-\mathrm{C} \alpha$
$\mathrm{K}_{\mathrm{a}}=\frac{\mathrm{C} \alpha^2}{1-\alpha}$
$1-\alpha \approx 1 \Rightarrow \mathrm{K}_{\mathrm{a}}=\mathrm{C}^2$
$\alpha=\sqrt{\frac{\mathrm{Ka}^2}{\mathrm{C}}}=\sqrt{\frac{6.25 \times 10^{-5}}{0.1}}=25 \times 10^{-3}$
$\mathrm{~V} . \mathrm{f} .(\mathrm{i})=1+\alpha(\mathrm{n}-1)=1+\alpha(2-1)=1+\alpha$
$=1+25 \times 10^{-3}=1.025$
$\Delta \mathrm{T}_{\mathrm{r}}=i \mathrm{~K} \mathrm{~m}$
$=(1.025)(1.86)(0.1)$
$=0.19$
$=19 \times 10^{-2}$
(નજીકનાં પૂર્ણાંકમાં રાઉન્ડ ઑફ) $\left[ K _{ b }=0.52 \,K \,kg \,mol ^{-1}\right]$