Question 15 Marks
In an intrinsic semiconductor the energy gap $E_{g}$ is $1.2eV$. Its hole mobility is much smaller than electron mobility and independent of temperature. What is the ratio between conductivity at $600K$ and that at $300K$? Assume that the temperature dependence of intrinsic carrier concentration $n_i$ is given by,
$\text{n}_{\text{i}}=\text{n}_{\text{0}}\ {\text{exp}}\Big(-\frac{\text{E}_\text{g}}{2{\text{K}_{\text{B}}}{\text{T}}}\Big)$
where $n_0$ is a constant.
$\text{n}_{\text{i}}=\text{n}_{\text{0}}\ {\text{exp}}\Big(-\frac{\text{E}_\text{g}}{2{\text{K}_{\text{B}}}{\text{T}}}\Big)$
where $n_0$ is a constant.
Answer
View full question & answer→Energy gap of the given intrinsic semiconductor $, E_g = 1.2 eV$
The temperature dependence of the intrinsic carrier $-$ concentration is written as: $\text{n}_{\text{i}}=\text{n}_{\text{0}}\ {\text{exp}}\Big[-\frac{\text{E}_\text{g}}{2{\text{K}_{\text{B}}}{\text{T}}}\Big]$
Where $, K_B =$ Boltzmann constant $= 8.62 \times 10^{-5} eV/K T$
$ =$ Temperature $n_0 =$ Constant Initial temperature $, T_1 = 300 K$
The intrinsic carrier $-$ concentration at this temperature can be written as: $\text{n}_{\text{i1}}=\text{n}_{\text{0}}\ {\text{exp}}\Big[-\frac{\text{E}_\text{g}}{2{\text{k}_{\text{B}}}\times300}\Big]...(1)$
Final temperature $, T_2 = 600 k$
The intrinsic carrier $-$ concentration at this temperature can be written as:
$\text{n}_{\text{i2}}=\text{n}_{\text{0}}\ {\text{exp}}\Big[-\frac{\text{E}_\text{g}}{2{\text{k}_{\text{B}}}\times600}\Big]...(2)$
The ratio between the conductivities at $600 K$ and at $300 K$ is equal to the ratio between the respective intrinsic carrier $-$ concentrations at these temperatures.
$\frac{\text{n}_{\text{i2}}}{\text{n}_{\text{i1}}}=\frac{\text{n}_\text{0}\ \text{exp}\Big[-\frac{\text{E}_{\text{g}}}{2\text{K}_{\text{B}}600}\Big]}{\text{n}_\text{0}\ \text{exp}\Big[-\frac{\text{E}_{\text{g}}}{2\text{K}_{\text{B}}300}\Big]}$
$=\text{exp}\frac{\text{E}_\text{g}}{2\text{k}_\text{g}}\bigg[\frac{1}{300}-\frac{1}{600}\bigg]$ $=\text{exp}\bigg[\frac{1.2}{2\times8.62\times10^{-5}}\times\frac{2-1}{600}\bigg] $
$= \text{exp} [11.6] = 1.09 \times 10^5$
Therefore, the ratio between the conductivities is $1.09 \times 10^5$.
The temperature dependence of the intrinsic carrier $-$ concentration is written as: $\text{n}_{\text{i}}=\text{n}_{\text{0}}\ {\text{exp}}\Big[-\frac{\text{E}_\text{g}}{2{\text{K}_{\text{B}}}{\text{T}}}\Big]$
Where $, K_B =$ Boltzmann constant $= 8.62 \times 10^{-5} eV/K T$
$ =$ Temperature $n_0 =$ Constant Initial temperature $, T_1 = 300 K$
The intrinsic carrier $-$ concentration at this temperature can be written as: $\text{n}_{\text{i1}}=\text{n}_{\text{0}}\ {\text{exp}}\Big[-\frac{\text{E}_\text{g}}{2{\text{k}_{\text{B}}}\times300}\Big]...(1)$
Final temperature $, T_2 = 600 k$
The intrinsic carrier $-$ concentration at this temperature can be written as:
$\text{n}_{\text{i2}}=\text{n}_{\text{0}}\ {\text{exp}}\Big[-\frac{\text{E}_\text{g}}{2{\text{k}_{\text{B}}}\times600}\Big]...(2)$
The ratio between the conductivities at $600 K$ and at $300 K$ is equal to the ratio between the respective intrinsic carrier $-$ concentrations at these temperatures.
$\frac{\text{n}_{\text{i2}}}{\text{n}_{\text{i1}}}=\frac{\text{n}_\text{0}\ \text{exp}\Big[-\frac{\text{E}_{\text{g}}}{2\text{K}_{\text{B}}600}\Big]}{\text{n}_\text{0}\ \text{exp}\Big[-\frac{\text{E}_{\text{g}}}{2\text{K}_{\text{B}}300}\Big]}$
$=\text{exp}\frac{\text{E}_\text{g}}{2\text{k}_\text{g}}\bigg[\frac{1}{300}-\frac{1}{600}\bigg]$ $=\text{exp}\bigg[\frac{1.2}{2\times8.62\times10^{-5}}\times\frac{2-1}{600}\bigg] $
$= \text{exp} [11.6] = 1.09 \times 10^5$
Therefore, the ratio between the conductivities is $1.09 \times 10^5$.


























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